IR
 

CSIR-CSMCRI Digital Repository >
S & T Publication >
Theses >

Please use this identifier to cite or link to this item: http://ir.csmcri.org/handle/1968424/73

Title: Synthesis and Characterization of Chiral Inorganic Metal Complexes as Active Catalysts for Enantioselective Synthesis of Chiral Beta-Amino alcohols via Epoxide-Ring Opening Reaction
Authors: Prathap, K.Jeya
Keywords: catalysis
Issue Date: 16-Nov-2011
Abstract: an efficient synthetic strategy for the preparation of new chiral macrocyclic Cr(III) salen complexes has been demonstrated. Among all the complexes prepared complex 34 showed excellent activity and enantioselectivity in AKR of racemic trans epoxides and ARO of meso epoxides with anilines as nucleophile at RT and the results are found to be superior than the monomeric and polymeric Cr(III) salen complexes as reported earlier for these reactions. Additionally, the macrocyclic Cr(III)salen complex 34 was efficiently recovered and reused several times and scaled up to 10 mmol.
URI: http://hdl.handle.net/1968424/73
Appears in Collections:Theses

Files in This Item:

File Description SizeFormat
K Jeya Prathap 2011 full thesis.pdf7.85 MBAdobe PDFView/Open
View Statistics

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

 

Valid XHTML 1.0! CSIR-CSMCRI IR Copyright © 2002-2010  Visit Us
Address:- Gijubhai Badheka Marg, Bhavnagar - 364021, Gujarat, INDIA - Feedback